Chapter 2.6

Safety in Laser Cleaning

 

Edited by Martin Cooper

The Conservation Centre, National Museums Liverpool, Whitechapel, Liverpool, L1 6HZ, United Kingdom

 

Contents

2.6.1    Introduction

2.6.2    Hazards of Laser Cleaning Systems

    2.6.2.1    Laser Beam Hazards

    2.6.2.2    Debris Generated During the Cleaning Process

    2.6.2.3    Noise Hazards

    2.6.2.4    Electric and Fire Hazards

2.6.3    Laser Classification

2.6.4    Safety Controls

    2.6.4.1    Administrative Controls

    2.6.4.2    Engineering Controls

    2.6.4.3    Personal Protective Equipment

2.6.5    Practical lLaser Safety

2.6.6    Summary of Safe Working Practice

    2.6.6.1    General

    2.6.6.2    Laser Environment

    2.6.6.3    Personal Protection

2.6.7    Supporting Information

    2.6.7.1    Laser Safety Standards

    2.6.7.2    Institutions and Organisations

    2.6.7.3    Laser Safety on the Web

    2.6.7.4    Laser Safety Publications

    2.6.7.5    Laser Safety Consultancy and Training

    2.6.7.6    Laser Cleaning

2.6.8    Acknowledgements

2.6.9    Contact Information

 

2.6.1          Introduction

Laser radiation is a unique form of light that can be utilised to clean delicate and valuable artworks in an extremely selective and controllable manner. The properties of laser radiation that make laser cleaning such a valuable technique for the conservator also give rise to hazards that must be properly controlled to ensure a safe working environment. Laser safety within the European Union is covered by a common standard, EN 60825-1 (Safety of laser products part 1; equipment classifi­cation, requirements and user’s guide). This chapter provides an introduction to those working with lasers in conservation as to how EN 60825-1 can be implemented so that safe working practices are followed. It is important to note here the new user guidelines IEC TR 60825-14 (Safety of laser products part 14: a user’s guide), which give advice to users on laser hazards, risk assessment and protective control measures. It is intended to replace the user guidelines in EN 60825-1, leaving the latter purely as a product compliance standard. Although all reasonable effort has been made to ensure the accuracy of the information contained in this chapter, it should not replace the require­ments of international and national standards, national laws and regulations and formal advice received from safety consultants.

2.6.2          Hazards of laser cleaning systems

The unique properties of a laser beam give rise to certain hazards, which must be controlled to ensure safe working. Laser radiation entering the eye can cause permanent damage and the low divergence of a laser beam means that energy can be delivered over relatively large distances with very little change to its properties. A laser beam can therefore remain hazardous a long way from its source. In addition to hazards from the laser beam itself, hazards associated with use of the laser beam for cleaning also exist: ejection of particulates and vapours from the surface and noise gener­ated by equipment and the cleaning process. The hazards associated with the use of laser cleaning systems in conservation are outlined here.

2.6.2.1       Laser beam hazards

Ocular hazards

The eye is an extremely sensitive and important part of the body. The ability of the eye to collect and focus light means that it is vulnerable to laser-induced damage. Damage can occur at all wave­lengths, although the area of tissue affected is wavelength-dependent (Tab. 2.6.1). Laser radiation emitted in the visible (400 – 700 nm) and near infrared (700 – 1400 nm) spectral regions poses the greatest risk as light is transmitted effectively through the liquid in the eye and focused to an extremely small spot on the retina at the back of the eye. This wavelength range is known as the retinal hazard region.

This high concentration of energy can be sufficient to damage the retina permanently. This damage can be especially serious if it occurs to the central region (fovea) of the retina, which contains a particularly high concentration of light sensors. Damage here can seriously affect the sight in that eye. Unfortunately, most accidents occur with the viewer looking in the direction from which the laser beam has travelled and damage to the eye is, therefore, most likely to occur in this critical region.

Laser radiation at short wavelengths (<300 nm) in the ultraviolet and in the far infrared (>3000 nm) regions is absorbed at the front of the eye, which can cause damage to the cornea. Laser radiation in the middle infrared (1400 – 3000 nm) and near ultraviolet (300 – 400 nm) regions is absorbed mainly by the lens, which can lead to formation of a cataract.

Even short exposures to a high intensity laser beam can cause damage. This is partly due to the fact that the duration of laser pulses used in cleaning applications (typically 10 ns) is extremely short compared to the time needed for protection afforded by the blink reflex (approximately 0.1 s). This means that injury can be caused by a single pulse.

Tab. 2.6.1:  Wavelength-dependence of laser damage to the eye.

Wavelength region

Part of eye susceptible to laser damage

Ultraviolet

(<300 nm)

Cornea

Near ultraviolet

(300 – 400 nm)

Lens

Visible

(400 – 700 nm)

Retina

Near infrared

(700 – 1400 nm)

Retina

Middle infrared

(1400 – 3000 nm)

Lens

Far infrared

(>3000 nm)

Cornea

 

Skin hazards

Laser radiation can also cause injury to skin, though in general skin hazards are considered to be less serious than eye hazards. The part of the skin affected will depend on the wavelength of the laser beam. Visible and near infrared (400 – 1400 nm) radiation is able to penetrate into the epider­mis (50 – 150 µm from surface) and dermis (1 – 4 mm), whereas far ultraviolet and far infrared radiation is absorbed strongly in the stratum corneum (8 – 20 µm). Potential effects of irradiation of skin by a laser beam are summarised in Tab. 2.6.2.

Tab. 2.6.2: Summary of the effects of a laser beam on skin.

Wavelength region

Skin effects

Ultraviolet

(200 – 400 nm)

Erythema (sunburn)

Skin cancer

Accelerated skin ageing

Increased pigmentation

Pigment darkening

Skin burn

Visible

(400 – 780 nm)

Photosensitive reactions

Skin burn

Infrared

(780 – 10000 nm)

Skin burn

 

2.6.2.2       Debris generated during the cleaning process

Laser cleaning may involve evaporation, smoke-generating pyrolysis, melting, and/or spalling of the layer to be removed. These waste products are composed mainly of material removed from the substrate. In addition, small amounts of compounds that were not part of the original material, gases generated by thermal cracking of organic substances and their eventual combustion, can be created. These laser-generated air contaminants are known to create objectionable odours and visible smoke. Removal of some organic materials may release potentially harmful bacteria, fungae (hyphae and spores) into the vicinity. The human response to chemicals depends on several factors, including the type of chemical, its concentration and form, and the individual (age, sex, genetics, health, etc.). Some chemicals are irritants, some cause immune responses for allergic persons, and some can be the cause of disease after many years of exposure.

Debris resulting from the removal of sulphation crusts by laser cleaning can include a significant proportion of particles with diameters of 3 µm or less. Such small particles can penetrate the lungs down to the alveoles, and are potentially harmful by solubilization of their alkaline and metallic salt compounds. Such small particles are also able to enter the body through the skin.

2.6.2.3       Noise hazards

There are three sources of noise at laser cleaning workplaces:

— the laser system itself,

— the fume extraction device, and

— the laser cleaning process.

The rapid ejection of material from a surface during laser cleaning leads to the generation of sound waves, which propagate away from the surface and are heard as a ‘snapping’ sound. The long term effects of exposure to all three sources of noise together have not yet been investigated.

2.6.2.4       Electric and fire hazards

High voltage electrical equipment is often contained inside a laser. This does not normally pose a hazard unless the protective covers of the laser are removed. Extreme caution should be exercised during maintenance and servicing when the covers of the laser cleaning system may be removed. Maintenance and servicing of lasers should only be carried out by people who have received appro­priate training. Most laser cleaning systems use water in the cooling system, which would create a serious hazard if allowed to come into contact with the electrical equipment inside a laser. Under normal conditions, this will not happen but, of course, great care should be taken during mainte­nance and servicing. Fire hazards may be the consequence of electrical faults, or may be due to ignition of flammable materials by the laser beam, as reported in some medical applications.

2.6.3          Laser classification

A laser cleaning system, as with all devices incorporating a laser, is assigned to a product class according to the potential of its accessible laser emission for causing injury. These product classes are detailed in the European standard IEC 60825-1. The product classes are outlined in Tab. 2.6.3.

The classification of a laser product depends on the accessible laser emission. A product may be assigned to class 1 if its output power is too low to be considered hazardous, or if the engineering design of the product is such that it is not possible, under reasonably foreseeable conditions of use, to access the laser radiation. A class 4 laser may be embedded in a product, which is assigned to class 1, if the design of the product meets the safety requirements detailed in IEC 60825-1 (Fig. 2.6.1). Most laser cleaning systems used in conservation are class 4, i.e. their use requires extreme care. The type of laser radiation used to clean the surface of an artwork is unsafe and the nature of the work usually requires that the laser beam be delivered through a flexible handheld optical fibre or articulated arm (Fig. 2.6.2). It is important to note that modifications to a system may lead to a change to its classification and hence to the safety controls appropriate to its use. Maintenance work may also necessitate the implementation of additional safety controls.

Table 2.6.3: Summary of laser classification (for a full description see IEC 60825-1 or the equivalent national standard). Most laser cleaning systems are class 4.

Laser class

Explanation

1

Safe under reasonably foreseeable conditions of use.

1M

Same as for class 1, but unsafe if magnifying viewing instru­ments are used, e.g. telescopes, microscopes etc.

2

Safe for accidental brief viewing.  Protection afforded by blink reflex of eye.

2M

Same as for class 2, but unsafe if magnifying viewing instru­ments are used.

3R

Unsafe for eye, but risk of injury low unless viewing prolonged.

3B

Direct viewing of the beam or specular reflections is hazardous.  Viewing of diffuse reflections may be safe.

4

Unsafe.  Viewing of the direct beam, specular reflections and diffuse reflections is hazardous.  May also pose hazards to the skin and their use may create fume and fire hazards. Use requires extreme care.

 

2.6.4          Safety controls

In order to establish the precautions necessary for safe working with lasers it is necessary to identify the hazards and to establish the level of risk (a combination of the likelihood of harm occurring and the severity of injury that would result). This is achieved by way of a risk assessment (health and safety at work legislation requires that a risk assessment is carried out for all work-related hazards). The risk assessment will need to identify all hazards, establish the conditions under which these hazards may exist and identify the level of risk to which people may be exposed. Appropriate safety controls can then be put in place to reduce the level of risk to an acceptable level. Both the risk assessment and safety controls should be documented. There must be a formal written framework within which laser safety is managed by the organisation.

A Laser Safety Officer (LSO) should be appointed to take administrative responsibility of laser safety on behalf of the employer and to ensure compliance with safe working procedures. The role of the LSO includes ensuring appropriate control measures are in place, regular monitoring of laser hazards and the effectiveness of the control measures implemented and maintenance of records of such monitoring. The role of the LSO should also include the specific approval of control measures. This is especially important with outdoor cleaning where the safety installation will be temporary and conditions may be far from ideal.

The safe use of laser cleaning systems in conservation requires adoption of a number of safety controls, governed largely by the classification of the system. These are divided into three main areas: administrative, engineering and personal protective equipment. The controls outlined here should be implemented for a class 4 product (most laser cleaning systems currently in use in conservation are class 4).

2.6.4.1          Administrative controls

Administrative controls are concerned with controlling who uses the laser cleaning system and how it is used. The procedural aspects of the administrative controls, i.e. the ‘local rules’, are extremely important as these establish the organisational framework within which the laser will be used. Use of a laser cleaning system should, therefore, be restricted to personnel who have received training in safe use of lasers. Access to the laser system should be controlled through a key or password entered via the control panel. Keys should be stored in a separate area from the cleaning system.

2.6.4.2          Engineering controls

Engineering controls are concerned with maintaining the laser beam within a ‘controlled’ area, making access to the ‘controlled’ area safe and use of equipment to remove by-products of the cleaning process from the work-area. Most laser cleaning systems produce a diverging laser beam. As the laser beam travels away from the system, eventually it will spread out to such a large extent that it can be considered safe, i.e. it has become too weak to damage the eye. This distance is referred to as the Nominal Ocular Hazard Distance (NOHD). The NOHD is dependent on the characteristics of the laser cleaning system being used, including wavelength, pulse length, pulse energy and beam divergence. The NOHD for laser cleaning systems in conservation may range from tens of metres to hundreds of metres. Practically, this means that laser cleaning should be carried out within a controlled area, within which the laser beam is confined. Appropriate warning signs and a warning light (activated when the laser is in operation) should be clearly visible. Inter­locks should be installed at points of access to the controlled area so that the laser system is turned off when someone enters the area. When setting up a controlled area (either within a large studio or on-site), the path of a laser beam escaping from the area (if a roof has not been included) should always be considered: Specularly reflecting surfaces (e.g. shiny metal pipes) may exist above the work area or windows in the upper floors of a neighbouring building may be directly in the line of sight.  In such cases, the possibility exists of people outside the controlled area inadvertently being exposed to hazardous radiation and so a roof should be included. Special care should be taken on scaffolding to ensure gaps between scaffold boards are covered or filled, if work is taking place either above or below the laser cleaning area. Particulates and fumes generated by the cleaning process should be extracted at source.

2.6.4.3          Personal protective equipment

The use of personal protective equipment (PPE) is necessary where protection cannot be guaranteed by the implementation of appropriate administration and engineering controls, which is almost always the case in conservation. Since the direct laser beam and both specular and diffuse reflec­tions generated from the surface of an artwork during laser cleaning are hazardous to the operator, PPE in the form of protective eyewear is essential. Such eyewear is available from specialist manu­facturers in the form of spectacles or goggles (Fig. 2.6.3). Eyewear must provide adequate protec­tion at the wavelength being used (EN 207 covers laser protective eyewear); this means that changing the wavelength of the emitted beam will usually necessitate a change in protective eye­wear. The protection level required is determined by the characteristics of the laser system being used: wavelength, pulse length, maximum pulse energy, maximum repetition rate and beam divergence. It is recommended to wear long sleeves and gloves to provide additional protection from fine particulates entering the body through the skin (Fig. 2.6.3). Working at ultraviolet wave­lengths may necessitate skin protection from the associated beam hazard.

2.6.5          Practical laser safety

In addition to the controls outlined in section 4 attention should be paid to other factors, such as avoiding exposure of skin, quality of illumination, presence of shiny surfaces, covering windows within a controlled area, number of people within the controlled area and general hygiene.

Laser radiation can pose a hazard to the skin. It is, therefore, important to avoid exposure of skin to the laser beam. At infrared wavelengths simple avoidance by careful aiming of the laser beam at the target is usually sufficient. Prolonged cleaning at ultraviolet wavelengths, however, may require protection of the skin from diffuse reflections.

The workplace should be well-illuminated. This allows the conservator to see the work properly (especially when wearing tinted eye protection), to move around the work area freely and see other hazards such as trailing cables. Ideally, the walls surrounding the workplace should be light coloured and diffusely reflecting. The work area should ideally be well-ventilated.

Specularly reflecting surfaces should be removed from the workplace to reduce the chance of stray reflections. Conservation tools, e.g. scalpels and paint brushes often have shiny surfaces; these should be covered with non-reflecting tape. Care should be taken when wearing jewellery during laser cleaning operations. If the boundaries of the controlled area contain windows then these should be covered using a material, which is opaque to the laser radiation being used (glass trans­mits most of the wavelengths used in laser cleaning very efficiently). Attention should also be paid to the number of people present in the controlled area. Ideally, only one laser should be used at one time and no other work should be undertaken while the laser is in use. If it is necessary to use more than one laser cleaning system simultaneously, then a controlled area should be created for each laser.

The beam from a class 4 laser can in certain situations set fire to flammable materials. It is, there­fore, important to keep all such materials including cleaning solvents away from the beam. It would be prudent to install a suitable fire extinguisher in the work area.

As with other conservation procedures, general health and safety practice should be followed, i.e. no eating, drinking or smoking in the workplace; wash hands and face following laser cleaning work. Immediate work areas should be cleaned (using HEPA class filtration industrial vacuum cleaners) following laser cleaning to prevent accumulation of fine particulate matter. The whole of the laser cleaning area should be cleaned at regular intervals.

Laser cleaning for excessive lengths of time can lead to eye strain, in much the same way as prolonged working at a computer screen. Tolerance levels vary from person to person but intense concentration on a small area for an extended period of time can become tiring. Regular breaks (which may simply involve stopping for a few seconds to allow eye muscles time to relax) should be taken.

Fig. 2.6.4 shows the laser cleaning set-up in the sculpture department of a national museum in the United Kingdom. A controlled area for laser cleaning has been established in a separate room located next to the main sculpture studio. Waste material generated during the cleaning process is removed using the in-built extraction unit by positioning the extraction hood close to the work area. The workplace is well lit. The conservator is wearing protective eyewear and a face mask.

Figs. 2.6.5 – 2.6.7 show laser cleaning on scaffolded sites, where either tin hoarding or opaque plastic sheeting has been used to create a controlled area within which laser cleaning is able to proceed safely. As with working in a studio environment, safe working procedures must be set up prior to work commencing. All conservators who will be working on site must fully understand and comply with the procedures. For site work it is often necessary to have several conservators working at the same time. In such situations it is recommended that the laser work area and non-laser work area are separated by an opaque screen and warning signs are clearly visible. It is important that people cannot accidentally walk into a laser work area. Care must also be taken to ensure that conservators working on a level above or below that where cleaning is being undertaken are not put at risk through gaps between the different levels. All contractors should be made aware of the laser work being carried out and the safety requirements of the laser cleaning contractor should be established at the earliest opportunity to avoid delays and additional costs at a later stage.

 

It is important to stress that the LSO should be responsible for approving outdoor installations before work commences.

2.6.6       Summary of safe working practice

This is intended to provide a brief summary of good safe working practice for conservators under­taking laser cleaning activities with a class 4 laser cleaning system, emitting visible or near infrared radiation.

2.6.6.1       General

— Written procedures based on the findings of a risk assessment should be in place and followed.

— Potential users of laser systems must receive appropriate training before being allowed to start laser cleaning work.

— Servicing and maintenance of laser cleaning systems must only be carried out by people who have received appropriate training and have relevant expertise.

— Store keys to laser cleaning systems away from the systems.

— Appoint Laser Safety Officer.

— Regularly check safety controls and ensure compliance among staff.

— Take regular breaks during laser cleaning activities to avoid eye/muscle strain.

— Only one person should be working within the controlled area at any time (anyone else should only be observing).

— Consult with Laser Protection Adviser (possibly expert from outside organisation) if extra advice required.

2.6.6.2       Laser environment

— Laser cleaning should be carried out in a controlled area within which the laser beam is confined.

— If there is no roof to the controlled area, ensure that the laser beam cannot pose a hazard to people within the nominal ocular hazard area.

— Ensure windows covered by material opaque to the wavelength(s) being used.

— Ensure laser warning signs and warning light are clearly visible.

— Ensure access to controlled area is restricted; use interlocks if possible. Inadvertent entry into the controlled area should not be possible.

— The work area should be well-illuminated.

— Remove shiny objects, e.g. scalpels, from the vicinity of the object being cleaned.

— Only one laser cleaning system should be used within a single controlled area.

— Do not put water containers on top of the laser cleaning system.

— Use localised extraction to remove debris at source. Ensure equipment used correctly and filters changed when necessary.

— Ensure all power cables, leads etc. do not present tripping hazard.

— Clean the work area regularly to avoid accumulation of debris over time.

2.6.6.3       Personal protection

— Wear appropriate laser safety eyewear.

— Ensure eyewear fits correctly.

— Clean eyewear only with appropriate fluid and soft tissue/cloth.

— Store eyewear carefully to avoid damage.

— Replace eyewear if damaged.

— If changing wavelength, ensure correct eyewear in place before starting work.

— Ensure all people inside controlled area are wearing safety eyewear at all times while laser is operating.

— Avoid exposure of skin to laser radiation.

— Wear an appropriate face mask during cleaning.

2.6.7       Supporting information

2.6.7.1       Laser safety standards

EN 60825-1: Safety of laser products Part 1: Equipment classification, requirements and user’s guide.

This is the main European safety standard for laser products.

IEC TR 60825-14: Safety of laser products part 14 (user’s guide).

Advice on laser hazards, risk assessments and control measures. Intended to replace user’s guidelines in EN 60825-1. Published in the U.K.

EN 207: Personal eye protection – filters and eye protectors against laser radiation (laser eye protectors)

European standard defining performance and testing requirements for laser protective eyewear.

CLC/TR 50448 (European document due to be published)

Guide to levels of competence required in laser safety.

2.6.7.2       Institutions and organisations

British Standards Institute (BSI):  www.bsi-global.com

European Agency for Safety and Health at Work (EASHW): http://agency.osha.eu.int

International Committee on Non-Ionising Radiation Protection (ICNIRP): www.icnirp.de               

International Electrotechnical Commission (IEC):  www.iec.ch

International Standardization Organization (ISO): www.iso.ch

Health Protection Agency:  www.hpa.org

2.6.7.3       Laser safety on the web

A Brief Guide to Laser Safety: http://www.bioptica.co.uk/laser_safety.htm

General rules and precautions with references for further reading.

 

Elements of Laser Safety: http://gary.myers.net/elements.htm

Mainly discusses how the human body, especially the eye, can be affected by various frequencies of laser radiation.

 

Handbook of Industrial Laser Safety: http://info.tuwien.ac.at/islt/safety

Information on laser radiation, laser hazards, gas and fume emission, risk assessment, training and education, safety standards.

 

Laser Accidents:  http://www.adm.uwaterloo.ca/infohs/lasermanual/documents/section11.html
Summaries of reported laser accidents in the
United States and their causes from 1964 to 1992. They indicate that the majority of injuries involve the eye and occur during alignment procedures, or because the protective eyewear was either inappropriate or not used.

 

Laser Hazards:  http://www.adm.uwaterloo.ca/infohs/lasermanual/documents/section6.html

Eye and skin hazards from laser light.

 

Laser Institute of Americawww.laserinstitute.org/safety_bulletin/lsib/

 

Lasers in Health Care:  http://www.ccohs.com/oshanswers/phys_agents/lasers.html

Questions and answers on the use of lasers in health care.

 

Non-Beam Laser Hazards: http://www.adm.uwaterloo.ca/infohs/lasermanual/documents/section7.html

Various electrical, radiation, fire, explosion and chemical hazards.

 

Rockwell Laser Industries: http://www.rli.com/

Laser safety consulting, training and a full line of safety products including eyewear, barriers, signs, hazard analysis software and instructional materials. Site includes much safety related information

2.6.7.4          Literature

Laser Safety, by Roy Henderson and Karl Schulmeister, Institute of Physics Publishing, Bristol, January 2004, ISBN 0750308591.

 

Handbook of Industrial Laser Safety (CD), by Karl Schulmeister, Thomas Puester, Mike Green and Roy Henderson, Austrian Research Center Seibersdorf: http://info.tuwien.ac.at/islt/safety

 

Industrial Laser Safety, edited by Mike Green (Prolaser Consultants), Summary of Eureka project EU 643 ‘Safety in the Industrial Applications of Lasers’ (1992-1996).

 

Cleaning safely with a laser in artwork conservation

COST Action G7, Booklet on safety in laser cleaning for conservators, 2006.

2.6.7.5          Laser safety consultancy and training

Association of Industrial Laser Users:  www.ailu.org.uk

Austrian Research Centre Seibersdorf:  www.healthphysics.at/laser

Bioptica:  www.bioptica.co.uk

Irepa Laser:  www.irepalaser.fr

Prolaser Consultants:  www.prolaser.co.uk

2.6.7.6          Laser Cleaning

EU COST Action G7: 'Artwork Conservation by Laser': http://alpha1.infim.ro/cost/

2.6.8          Acknowledgements

This chapter has been taken from ‘Cleaning safely with a laser in artwork conservation’, a booklet produced for conservators as part of COST Action G7 ‘Artwork Conservation by Laser’. The editor is grateful to the COST G7 members for their contribution to this booklet, particularly Veronique Vergès-Belmin, Margarida Pires, Renzo Salimbeni, Johann Nimmrichter, Alain Diard and Martin Labouré. Photographs have been reproduced with kind permission of National Museums Liverpool (United Kingdom), Laserblast (Quantel, France) and Johann Nimmrichter, Bundesdenkmalamt Department of Conservation (Vienna, Austria).

2.6.9          Contact information

The Conservation Centre

National Museums Liverpool

Whitechapel

Liverpool L1 6HZ

United Kingdom

E: martin.cooper@liverpoolmuseums.org.uk