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Chemiluminescence
will enable the conservation scientist to study the oxidative degradation
reactions of paper. Even historic originals may be studied using the new
prototype with non-destructive sampling.
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1920's, IT WAS DISCOVERED that acidity in paper is harmful for its stability
and in the years to come, conservation treatments were proposed. It is
now well known that deacidification of acidic paper is the first step
towards long-term preservation. However, scientists and conservators so
far agree only to this point. Not even whether Ca- or Mg- containing deacidification
chemical should be used, is agreed upon. ¶
Once paper is neutral to moderately alkaline, autoxidation and alkaline
degradation become the predominant degradation mechanisms. The experimental
techniques available to conservation chemists are tedious and time-consuming
and months are needed to evaluate the stability of a particular type of
paper at room temperature. In addition, such evaluation is usually a subject
to a large error. Since chemiluminescence accompanies oxidation reactions,
the idea behind Papylum project is to construct an instrument, which will
enable the conservation scientist to study the degradation reactions of
neutral/alkaline paper at experimental temperatures close to room temperature
and correlate light emission with paper's stability. This will enable
us to:
Obtain a better knowledge of the
degradation reaction and propose better conservation procedures;
Provide an experimental method as an alternative to accelerated
ageing;
Evaluate paper conservation
procedures more quickly and with more confidence;
Study stability of historical artefacts using non-destructive
sampling.
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The new chemiluminometer Lumipol 3
prototype
produced by the Papylum team.
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